A diamantane-4,9-dicarboxylate based UiO-66 analogue: challenging larger hydrocarbon cage platforms

نویسندگان

چکیده

HHUD-3, based on a bulky barrel shaped ligand, possesses 35%+ missing linker defects, essential for accessible porosity. With S BET = 890 m 2 g ?1 (N ), HHUD-3 features higher CH 4 but lower CO and H adsorption compared to UiO-66.

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ژورنال

عنوان ژورنال: CrystEngComm

سال: 2022

ISSN: ['1466-8033']

DOI: https://doi.org/10.1039/d2ce01170k